全文获取类型
收费全文 | 242965篇 |
免费 | 79252篇 |
国内免费 | 46223篇 |
专业分类
电工技术 | 31348篇 |
技术理论 | 11篇 |
综合类 | 25894篇 |
化学工业 | 33895篇 |
金属工艺 | 28244篇 |
机械仪表 | 10731篇 |
建筑科学 | 16864篇 |
矿业工程 | 15033篇 |
能源动力 | 10220篇 |
轻工业 | 24229篇 |
水利工程 | 8402篇 |
石油天然气 | 16412篇 |
武器工业 | 4145篇 |
无线电 | 36541篇 |
一般工业技术 | 37131篇 |
冶金工业 | 9619篇 |
原子能技术 | 2005篇 |
自动化技术 | 57716篇 |
出版年
2024年 | 1355篇 |
2023年 | 5159篇 |
2022年 | 6276篇 |
2021年 | 7818篇 |
2020年 | 10464篇 |
2019年 | 19602篇 |
2018年 | 21217篇 |
2017年 | 22680篇 |
2016年 | 22308篇 |
2015年 | 21887篇 |
2014年 | 21125篇 |
2013年 | 21003篇 |
2012年 | 20381篇 |
2011年 | 17065篇 |
2010年 | 15417篇 |
2009年 | 12182篇 |
2008年 | 10327篇 |
2007年 | 9467篇 |
2006年 | 8588篇 |
2005年 | 7867篇 |
2004年 | 9665篇 |
2003年 | 8509篇 |
2002年 | 8589篇 |
2001年 | 7532篇 |
2000年 | 6572篇 |
1999年 | 6285篇 |
1998年 | 5337篇 |
1997年 | 4690篇 |
1996年 | 4402篇 |
1995年 | 4376篇 |
1994年 | 3613篇 |
1993年 | 3174篇 |
1992年 | 2990篇 |
1991年 | 2200篇 |
1990年 | 1715篇 |
1989年 | 1555篇 |
1988年 | 1212篇 |
1987年 | 407篇 |
1986年 | 335篇 |
1985年 | 242篇 |
1984年 | 160篇 |
1983年 | 117篇 |
1982年 | 168篇 |
1981年 | 160篇 |
1980年 | 125篇 |
1976年 | 229篇 |
1975年 | 205篇 |
1972年 | 235篇 |
1971年 | 128篇 |
1960年 | 205篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
81.
以微米级氧化钒(V2O5)、氧化铬(Cr2O3)和纳米碳黑为原料,采用机械合金化及微波辅助加热法制备了纳米碳化钒/碳化铬复合粉末。利用XRD、XPS、TG-DSC、SEM、TEM和BET对产物进行了分析表征。结果表明,:纳米碳化钒/碳化铬复合粉末的最佳合成条件为:碳的质量分数为35%,反应温度为900℃,保温时间为1h。在该条件下的反应产物主要由V3Cr2C5、Cr2VC2和Cr3C2组成,颗粒为球形或类球形,分散性较好,无明显团聚现象,平均颗粒尺寸约为50nm,复合粉末的比表面积为115.53m2/g。添加纳米碳化钒/碳化铬复合粉末可以提高陶瓷结合剂cBN磨具的力学性能和磨削效率,降低磨具的损耗,并且对磨具具有减摩作用。 相似文献
82.
83.
To improve the hydrophobicity of bagasse hemicellulose-based films, glutaraldehyde was applied when preparing films of original and cationic bagasse hemicellulose with the addition of polyvinyl alcohol and sorbitol. The results showed that the cationic modification could increase the hydrophobicity of the hemicellulose-based film, and the hydrophobicity of hemicellulose-based films crosslinked with glutaraldehyde also increased. However, cationic modification of hemicellulose decreased the stress of the hemicellulose-based film. While crosslinking with glutaraldehyde increased the stress of both the original and cationic hemicellulose-based films. Macrophotography indicated that the film formability of the original hemicellulose was better than that of cationic hemicellulose. Through SEM observation, the degree of bonding of different components of the films was found to be increased due to crosslinking with glutaraldehyde. The crosslinking reaction between glutaraldehyde and hemicellulose was further confirmed by FT-IR spectroscopy. 相似文献
84.
85.
Jun Yang Jing Na Guanbin Gao 《International Journal of Adaptive Control and Signal Processing》2019,33(12):1868-1884
This paper provides a modified model reference adaptive control (MRAC) scheme to achieve better transient control performance for systems with unknown unmatched dynamics, where an adaptive law with guaranteed convergence is introduced. We first revisit the standard MRAC system and analyze the tracking error bound by using L2‐norm and Cauchy‐Schwartz inequality. Based on this analysis, we suggest a feasible way to compensate the undesired transient dynamics induced by the gradient descent–based adaptive laws subject to sluggish convergence or even parameter drift. Then, a modified adaptive law with an alternative leakage term containing the parameter estimation error is developed. With this adaptive law, the convergence of both the estimation error and tracking error can be proved simultaneously. This enhanced convergence property can contribute to deriving smoother control signal and improved control response. Moreover, this paper provides a simple and numerically feasible approach to online verify the well‐known persistent excitation condition by testing the positive definiteness of an introduced auxiliary matrix. Comparative simulations based on a benchmark 3‐DOF helicopter model are given to validate the effectiveness of the proposed MRAC approach and show the improved performance over several other MRAC schemes. 相似文献
86.
This work aims to improve the rheological properties and stability of multiwalled carbon nanotubes (MWCNTs)/acrylamide (AA) base skeleton polymer blends at harsh environment of high salinity-high temperature (HS-HT) or various pH. Different co/terpolymers have been accomplished to modify the structure of AA polymer by free-radical copolymerization of AA-based monomers. Anionic, cationic, and hydrophobic functional groups were used for the synthesis of polyelectrolyte, polyampholytic, and partially hydrophobic AA polymer types. The conversion, molecular weight, and poly dispersity of co/terpolymers have been evaluated by nuclear magnetic resonance (1H-NMR), gel permeation chromatography, and differential scanning calorimetry analysis. The effects of sonication power, concentration of polymer, and concentration of MWCNTs were also investigated on rheological behavior of co/terpolymers. The results show that negative polyelectrolyte and polyampholytic polymers are the best candidates for the improvement of MWCNTs/polymer stability and viscosity at HS-HT and alkali environment, respectively. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47205. 相似文献
87.
为探究挠性筋结构单晶硅材料的各向异性特性以及KOH腐蚀工艺对其力学性能的影响规律,进行纳米压痕实验,并结合原子力显微镜观察单晶硅表层3个主晶面上压痕裂纹形貌随晶向的变化规律,分析单晶硅材料表层弹性模量、硬度、断裂韧性等机械力学特性参数在(001)、(110)及(111)3个主要晶面上沿各个晶向的变化规律;分析挠性筋结构单晶硅材料(001)晶面的KOH腐蚀工艺对其材料表面机械特性的影响规律.结果表明:挠性筋单晶硅在(001)晶面上弹性模量的各向异性变化幅度明显,硬度及断裂韧性各向异性的变化幅度不大;挠性筋单晶硅在(110)晶面弹性模量和断裂韧性的各向异性变化幅度明显,硬度各向异性变化幅度不大;挠性筋单晶硅在(111)晶面硬度值、弹性模量及断裂韧性参数的变化幅度幅值均较小;确定了单晶硅表层3个晶面裂纹最易扩展的晶向方向,KOH腐蚀工艺使得单晶硅表面质量降低,腐蚀后暴露的表面微裂纹、缺陷等会使得单晶硅(001)晶面表层硬度、断裂韧性降低,从而降低了挠性筋结构的实际断裂强度. 相似文献
88.
Ningbo Gao Kailun Chen Cui Quan Shixi Wu 《International Journal of Hydrogen Energy》2021,46(40):20882-20892
A novel catalyst, Nickel supported over MCM-41 coated ceramic membrane (NMC), was developed using coating method and deposition-precipitation method and applied for steam reforming of real tar in fixed bed. The effects of reaction conditions such as Ni loading amount, reaction temperature and mass ratio of steam to tar were also studied. The good dispersion of Ni nanoparticles and the strong interaction between Ni particles and the support were identified by BET, XRD, H2-TPR and SEM/EDS, resulting in the excellent performance of NMC catalysts. Maximum tar conversion of 96.4% and H2 yield of 98.7 mmol g?1 were obtained using 20NMC with a mass ratio of steam to coal tar of 2 at 800 °C. Moreover, 20 NMC exhibited a good stability in 10 h of lifetime test and the resistance of graphitic carbon formation prone to easier regeneration of catalysts illustrated by Raman spectroscopy. It indicates that the utilization of NMC catalysts for tar steam reforming is a promising way. 相似文献
89.
Xiaohong Hao Hang Suo Hui Peng Peixing Xu Xin Gao Su Du 《International Journal of Hydrogen Energy》2021,46(3):2890-2898
Microalgae is promising to be used as feedstock resources for hydrogen production due to its high oil and grease contents. This promotes the development of extraction technology of microalgae oil. In this study, based on the Rayleigh-Plesset equation, the effects of temperature, pressure, ultrasonic power and frequency on the bubble motion of ethanol ultrasound cavitation are investigated. Subsequently, the effects of different process parameters on the extraction rate are studied using Schizochytrium sp. as raw material by stirring or ultrasonic-assisted extraction. And the composition of algae extraction oil is analyzed. The results show that the amplitude of cavitation bubbles increases with the increase of ultrasonic power and decrease of ultrasonic frequency. The extraction rate of algae oil reaches 93.76 ± 0.48% when the ultrasonic power is 150 W, the reaction time is 30 min, the temperature is 50 °C and the liquid-solid ratio is 10:1. 相似文献
90.
Liyan Wen Gang Tao Bin Jiang 《International Journal of Adaptive Control and Signal Processing》2021,35(3):373-400
In this article, adaptive compensation designs are developed for nonlinear systems with uncertainties from the system functions and persistent actuator failures of characterizations that (i) some unknown system inputs are stuck at some unknown fixed or varying values at unknown time instants and (ii) the failure pattern always switches from one to another and the switching does not stop. Such a controlled plant is described by an uncertain time-varying nonlinear system, and some robust adaptive feedback linearization based failure compensation results are studied for closed-loop system stabilization and bounded output tracking for some specific conditions. To improve the tracking performance in the presence of persistent actuator failures, a new adaptive control scheme is developed, using the failure indicator function which contains the failure pattern and failure time in the formulation. Detailed stability and tracking performance are shown. Simulation results are shown to verify the effectiveness of the proposed adaptive actuator failure compensation method. 相似文献